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The boundaries between these regions are named the tropopause, stratopause and mesopause.
About 3.5 billion years ago, the surface had cooled enough to form a crust, still heavily populated with volcanoes releasing steam, carbon dioxide, and ammonia. This led to the "second atmosphere"; which was, primarily, carbon dioxide and water vapor, with some nitrogen and, virtually, no oxygen. This second atmosphere had ~100 times as much gas as the current atmosphere. It is generally believed that the greenhouse effect, caused by high levels of carbon dioxide, kept the Earth from freezing.
During the next couple billion years, water vapour condensed to form rain and oceans, which started to dissolve carbon dioxide. Approximately 50% of the carbon dioxide would be absorbed into the oceans. Photosynthesizing plants would evolve and convert carbon dioxide into oxygen. Over time, excess carbon became locked in fossil fuels, sedimentary rocks (notably limestone), and animal shells. As oxygen was released, it reacted with ammonia to create nitrogen; in addition, bacteria would also convert ammonia into nitrogen.
As more plants appeared, the levels of oxygen increased significantly (while carbon dioxide levels dropped). At first combined with various elements (such as [[iron); but, eventually the atmosphere began to "fill" with oxygen - resulting in mass extinctions and further evolution. The appearance of an ozone layer (a compound of oxygen atoms) lifeforms were better protected from ultraviolet radiation. This oxygen-nitrogen atmosphere is the "third atmosphere".
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